Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite
Само за регистроване кориснике
2017
Аутори
Kaluderović, Lazar M.Tomić, Zorica P.
Đurović-Pejčev, Rada
Vulić, Predrag J.
Asanin, Darko P.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86mmol/100g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch... equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM gt 1 CEC HM gt 1.5 CEC HM gt NaM.
Кључне речи:
X-ray diffraction (XRD) / Montmorillonite / hexadecyltrimethyl-ammonium bromide / batch equilibrium methodИзвор:
Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Wastes, 2017, 52, 5, 291-297Издавач:
- TAYLOR & FRANCIS INC, PHILADELPHIA
Пројекти:
- Минерали Србије: састав, структура, генеза, примена и допринос одржању животне средине (RS-MESTD-Basic Research (BR or ON)-176010)
- Проучавање биљних патогена, артропода, корова и пестицида у циљу развоја метода биорационалне заштите биља и производње безбедне хране (RS-MESTD-Technological Development (TD or TR)-31043)
DOI: 10.1080/03601234.2017.1281636
ISSN: 0360-1234
PubMed: 28277083
WoS: 000400353100001
Scopus: 2-s2.0-85012081846
Институција
Institut za pesticide i zaštitu životne sredineTY - JOUR AU - Kaluderović, Lazar M. AU - Tomić, Zorica P. AU - Đurović-Pejčev, Rada AU - Vulić, Predrag J. AU - Asanin, Darko P. PY - 2017 UR - https://ripest.pesting.org.rs/handle/123456789/399 AB - This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86mmol/100g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM gt 1 CEC HM gt 1.5 CEC HM gt NaM. PB - TAYLOR & FRANCIS INC, PHILADELPHIA T2 - Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Wastes T1 - Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite EP - 297 IS - 5 SP - 291 VL - 52 DO - 10.1080/03601234.2017.1281636 UR - conv_488 ER -
@article{ author = "Kaluderović, Lazar M. and Tomić, Zorica P. and Đurović-Pejčev, Rada and Vulić, Predrag J. and Asanin, Darko P.", year = "2017", abstract = "This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86mmol/100g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM gt 1 CEC HM gt 1.5 CEC HM gt NaM.", publisher = "TAYLOR & FRANCIS INC, PHILADELPHIA", journal = "Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Wastes", title = "Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite", pages = "297-291", number = "5", volume = "52", doi = "10.1080/03601234.2017.1281636", url = "conv_488" }
Kaluderović, L. M., Tomić, Z. P., Đurović-Pejčev, R., Vulić, P. J.,& Asanin, D. P.. (2017). Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Wastes TAYLOR & FRANCIS INC, PHILADELPHIA., 52(5), 291-297. https://doi.org/10.1080/03601234.2017.1281636 conv_488
Kaluderović LM, Tomić ZP, Đurović-Pejčev R, Vulić PJ, Asanin DP. Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Wastes. 2017;52(5):291-297. doi:10.1080/03601234.2017.1281636 conv_488 .
Kaluderović, Lazar M., Tomić, Zorica P., Đurović-Pejčev, Rada, Vulić, Predrag J., Asanin, Darko P., "Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite" in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Wastes, 52, no. 5 (2017):291-297, https://doi.org/10.1080/03601234.2017.1281636 ., conv_488 .